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The crystallinity and thermal degradation behaviour of polyamide 6/Oil Based Mud Fillers (PA6/OBMFs) nanocomposites
Polymer Degradation and Stability ( IF 6.3 ) Pub Date : 2018-11-10 , DOI: 10.1016/j.polymdegradstab.2018.11.004
Shohel Siddique , Lorraine Kwoffie , Kofi Addae-Afoakwa , Kyari Yates , James Njuguna

The crystallinity and thermal degradation behaviours of Polyamide 6/Oil Based Mud Fillers (PA6/OBMFs) nanocomposites have been investigated using differential scanning and thermogravimetry (TGA). The TGA indicates the onset decomposition temperature of D1/2 (half-decomposition) is 16 °C higher for PA6 with 10.0 wt% of OBMFs than that of PA6, whereas the lowest onset decomposition temperature difference among the nanocomposites and neat PA6 is 8 °C for PA6 with 7.5 wt% of OBMFs. However PA6 with 5.0 wt % OBMFs nanocomposite has taken the longest time (1 min 36 s more than neat PA6) to reach D1/2. It can be deduced in this study that PA6 with 5.0 wt % OBMFs nanocomposite provided the maximum heat resistant property whereas PA6 with 7.5 wt % OBMFs nanocomposite showed the maximum heat absorbance property among different nanocomposites and PA6 with 10.0 wt % exhibited the maximum thermal stability. There is a sigmoidal curve generated based on the TIF and wt% filler content value which shows three significant points at intersections of 50% TIF line which are highlighted as exfoliation (4.2 wt%), intercalation (6.8 wt%) and agglomeration (9.0 wt%) points. These TIF values explained the investigated heat resistant, heat capacity and thermal stability properties of PA6/OBMFs nanocomposites illustrating the ratio of TIF and MAF is the key measure which can be considered as an effective approach to identify the nanomorphology of PA6/OBMFs nanocomposites.



中文翻译:

聚酰胺6 /油基泥浆填料(PA6 / OBMFs)纳米复合材料的结晶度和热降解行为

聚酰胺6 /油基泥浆填料(PA6 / OBMFs)纳米复合材料的结晶度和热降解行为已使用差示扫描和热重分析(TGA)进行了研究。TGA表明,具有10.0 wt%OBMF的PA6的D1 / 2(半分解)的起始分解温度比PA6高16°C,而纳米复合材料和纯净PA6中最低的起始分解温度差为8°对于7.5重量%的OBMF,PA6为C。但是,具有5.0 wt%OBMFs纳米复合材料的PA6花费了最长的时间(比纯净的PA6多1分36秒)达到D1 / 2。在这项研究中可以推断出,具有5.0 wt%OBMFs纳米复合材料的PA6提供了最大的耐热性能,而具有7.5 wt%OBMFs纳米复合材料的PA6在不同的纳米复合材料中和具有10 wt%的PA6之间显示了最大的吸热性能。0重量%表现出最大的热稳定性。根据TIF和wt%填料含量值生成了一个S型曲线,该曲线在50%TIF线的交点处显示三个显着点,突出显示为剥落(4.2 wt%),插层(6.8 wt%)和结块(9.0 wt%)。 %)分。这些TIF值解释了所研究的PA6 / OBMFs纳米复合材料的耐热性,热容量和热稳定性能,说明了TIF和MAF的比例是关键指标,可被视为鉴定PA6 / OBMFs纳米复合材料纳米形态的有效方法。插层(6.8 wt%)和附聚(9.0 wt%)点。这些TIF值解释了所研究的PA6 / OBMFs纳米复合材料的耐热性,热容量和热稳定性能,说明了TIF和MAF的比例是关键指标,可被视为鉴定PA6 / OBMFs纳米复合材料纳米形态的有效方法。插层(6.8 wt%)和附聚(9.0 wt%)点。这些TIF值解释了所研究的PA6 / OBMFs纳米复合材料的耐热性,热容量和热稳定性能,说明了TIF和MAF的比例是关键指标,可被视为鉴定PA6 / OBMFs纳米复合材料纳米形态的有效方法。

更新日期:2018-11-10
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