Two-Dimensional Porous Polymers: From Sandwich-like Structure to Layered Skeleton,Accounts of Chemical Research

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Two-Dimensional Porous Polymers: From Sandwich-like Structure to Layered Skeleton
Accounts of Chemical Research ( IF 16.4 ) Pub Date : 2018-11-09 00:00:00 , DOI: 10.1021/acs.accounts.8b00444
Jinhui Zhu _{1,

2} , Chongqing Yang ₂ , Chenbao Lu ₂ , Fan Zhang ₂ , Zhanhui Yuan ₁ , Xiaodong Zhuang ₂

Affiliation

Inorganic porous materials have long dominated the field of porous materials due to their stable structure and wide applications. In the past decade, porous polymers have generated considerable interest among researchers because of their easily tunable porosity, carbon-rich backbones, and prominent physical properties. These attributes enable porous polymers to be used in various applications such as sensing, gas separation and storage, catalysis, and energy storage. However, poor dispersibility has long hindered the development of porous polymers. A majority of the reported porous polymers can only be synthesized with amorphous structure through direct precipitation from solutions during reactions. The rational design and synthesis of porous polymers with controllable morphology, such as two-dimensional (2D) morphology, remains great challenge.

中文翻译：

二维多孔聚合物：从三明治式结构到层状骨架

无机多孔材料由于其稳定的结构和广泛的应用长期以来一直主导着多孔材料领域。在过去的十年中，多孔聚合物因其易于调节的孔隙率，富碳主链和突出的物理性能而引起了研究人员的极大兴趣。这些属性使多孔聚合物可以用于各种应用中，例如传感，气体分离和存储，催化和能量存储。但是，分散性差长期阻碍了多孔聚合物的发展。大多数报道的多孔聚合物只能通过在反应过程中从溶液中直接沉淀而合成具有无定形结构。具有可控形态（例如二维（2D）形态）的多孔聚合物的合理设计和合成仍然是巨大的挑战。

更新日期：2018-11-09

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