Chemical Physics Letters ( IF 2.8 ) Pub Date : 2018-11-02 , DOI: 10.1016/j.cplett.2018.10.027 Wei Li , Sheng Qin , Qiyan Zhang , Zhikai Guo , Xiaoling Zhang
Rate constants at 253–328 K for reactions of OH radicals with (CF3)2CHOCH3 (k6), (CF3)2CHOCH2CH3 (k7), and (CF3)2CHOCH2CH2CH3 (k8) were studied using a relative rate method. Data on k6, k7, and k8 (2.13 × 10-13, 1.07 × 10-12, and 1.92 × 10-12 cm3 molecule-1 s-1, respectively) were obtained at 298 K. The corresponding radiative efficiencies (0.103, 0.034, and 0.021 W m-2 ppb-1) were calculated from infrared absorption spectra measured at room temperature. Global warming potential (GWP100) was estimated to be 5, < 1, and < 1, respectively, and the photochemical ozone creation potential in all cases was < 10.
中文翻译:
在253–328 K时与OH自由基的反应速率常数以及(CF 3)2 CHOC x H (2x +1)(x = 1,2,3)的大气影响
OH自由基与(CF 3)2 CHOCH 3(k6),(CF 3)2 CHOCH 2 CH 3(k7)和(CF 3)2 CHOCH 2 CH 2 CH 3( k8)是使用相对比率方法进行研究的。关于k 6,k 7和k 8(2.13×10 -13,1.07 ×10 -12和1.92×10 -12 cm 3分子-1 s -1的数据分别在298 K下获得。根据室温下测得的红外吸收光谱计算出相应的辐射效率(0.103、0.034和0.021 W m -2 ppb -1)。据估计,全球变暖潜能值(GWP 100)分别为5,<1和<1,在所有情况下光化学臭氧产生潜能值均小于10。