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TaCxOy: A photocatalytic promoter on g-C3N4 for visible-light Cr6+ reduction
Catalysis Communications ( IF 3.4 ) Pub Date : 2018-10-30 , DOI: 10.1016/j.catcom.2018.10.020
Nannan Zhang , Guangshe Li , Shuo Wang , Xingliang Xu , Liping Li

Graphitic carbon nitride (g-C3N4) is a promising visible light photocatalyst but bears low activity due to its high recombination rate of electron-hole pairs. Here, trace amorphous Ta2O5 modified TaC (TaCxOy) is in situ anchored on g-C3N4 (TaCxOy/g-C3N4) as an efficient photocatalyst to enhance charge separation. Introducing of TaCxOy endows TaCxOy/g-C3N4 with favorable band alignment and more exposed active sites. Specifically, 4.4 wt% TaCxOy/g-C3N4 embraces an optimal Cr6+ reduction conversion of 100% in 35 min, 49.3 and 2.4-fold enhancement, compared with bare TaCxOy and g-C3N4. Our work indicates that TaCxOy could be a promoter in water treatment and photo-energy conversion.



中文翻译:

TaC x O y:gC 3 N 4上的光催化促进剂,用于可见光中的Cr 6+还原

石墨碳氮化物(gC 3 N 4)是一种很有前途的可见光光催化剂,但由于其高的电子-空穴对复合率而具有较低的活性。在此,将痕量无定形Ta 2 O 5改性的TaC(TaC x O y)原位固定在gC 3 N 4(TaC x O y / gC 3 N 4)上,作为提高电荷分离的有效光催化剂。TaC x O y的引入赋予TaC x O y / gC 3 N 4具有良好的能带排列和更多暴露的活性位点。具体地,与裸露的TaC x O y和gC 3 N 4相比,4.4 wt%TaC x O y / gC 3 N 4包括在35分钟内100%的最佳Cr 6+还原转化率,49.3和2.4倍的增强。我们的工作表明TaC x O y可能是水处理和光能转化的促进剂。

更新日期:2018-10-30
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