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Visible light-induced direct conversion of aldehydes into nitriles in aqueous medium using [email protected]3N4 as photocatalyst
Catalysis Communications ( IF 3.7 ) Pub Date : 2018-10-30 , DOI: 10.1016/j.catcom.2018.10.031
Fooleswar Verma , Prashant Shukla , Smita R. Bhardiya , Manorama Singh , Ankita Rai , Vijai K. Rai

Unprecedented [email protected]3N4 catalyzed visible light driven efficient conversion of a variety of aldehydes into corresponding nitriles is reported. Operational simplicity, excellent yield of pure products (87–94%), ambient reaction condition, using aqueous methanol as solvent, visible-light photocatalysis are the salient features of envisaged methodology for direct conversion of aldehydes into nitriles. Furthermore, reusability of [email protected]3N4 was checked up to five runs and it was noticed that there was no substantial change in morphology as well as the catalytic efficiency of catalyst.



中文翻译:

可见光诱导的醛在水介质中直接转化为腈[使用电子邮件保护] 3 N 4作为光催化剂

据报道,空前的[受电子邮件保护] 3 N 4催化可见光可以有效地将各种醛转化为相应的腈。操作简便,纯净产品的优异收率(87–94%),环境反应条件,使用甲醇水溶液作为溶剂,可见光光催化是将醛直接转化为腈的方法学的突出特点。此外,检查了[电子邮件保护的] 3 N 4的可重复使用性,最多进行了5次,发现催化剂的形态和催化效率均没有实质性变化。

更新日期:2018-10-30
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