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Unexpected coke-resistant stability in steam-CO2 dual reforming of methane over the robust Mo2C-Ni/ZrO2 catalyst
Catalysis Communications ( IF 3.4 ) Pub Date : 2018-10-25 , DOI: 10.1016/j.catcom.2018.10.024
Panpan Ren , Zhongkui Zhao

A robust Mo2C-Ni/ZrO2 (Glu) catalyst was prepared by a glucose-assisted incipient wetness impregnation with subsequent reduction carburization method using glucose as carbon source (Glu-IWI-RCG), which demonstrated higher catalytic activity and unexpected stability in steam-CO2 dual reforming of methane (SCRM) for syngas production comparing with traditional Mo2C-Ni/ZrO2 (Met) catalyst prepared by conventional IWI followed by reduction carburization method using methane as metal dispersion promoting agent and carbon source. Various characterization techniques were employed to reveal the origin of its higher catalytic activity and unexpectedly higher stability in SCRM. The unexpected coke resistance of Mo2C-Ni/ZrO2 (Glu) allows it to be a practical candidate for syngas production via SCRM reaction.



中文翻译:

强大的Mo 2 C-Ni / ZrO 2催化剂在甲烷的蒸汽-CO 2双重整中具有意外的耐焦炭稳定性

葡萄糖辅助初湿浸渍法,以葡萄糖为碳源(Glu-IWI-RCG),采用还原还原渗碳法制备了一种稳健的Mo 2 C-Ni / ZrO 2(Glu)催化剂,具有较高的催化活性和出乎意料的稳定性。与传统IWI制备的传统Mo 2 C-Ni / ZrO 2(Met)催化剂相比较,然后使用甲烷作为金属分散促进剂和碳源的还原渗碳法,在蒸汽-CO 2甲烷双重整(SCRM)中用于合成气生产。采用了各种表征技术来揭示其更高的催化活性和出乎意料的更高的SCRM稳定性的起源。Mo的出乎意料的耐焦炭性2 C-Ni / ZrO 2(Glu)使其成为通过SCRM反应生产合成气的实际候选者。

更新日期:2018-10-25
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