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Nanoarchitectonics through supramolecular gelation: formation and switching of diverse nanostructures
Molecular Systems Design & Engineering ( IF 3.2 ) Pub Date : 2018-10-25 00:00:00 , DOI: 10.1039/c8me00068a
Yutao Sang 1, 2, 3, 4, 5 , Minghua Liu 1, 2, 3, 4, 5
Affiliation  

Supramolecular gels are currently an important class of soft materials that are attracting great interest. The gelation process has been proven to be a powerful approach for the construction of diverse and uniform architectures. Generally, these architectures are on the nanoscale and hierarchically self-assembled from small molecules. Nanoarchitectonics tries to bridge the gap between molecules and nanostructures, while supramolecular gelation provides a good platform to realize such a goal. While the design of the gelator molecules and the function of the gel are important topics, here, we focus on how small molecules can be fabricated into nanostructures through gelation, which is in fact the connection between the microstructures to the macroscopic functions. We showed meritorious examples of typical architectures constructed through the supramolecular gelation process. Then some examples showing the transformation or switching between different nanostructures are presented, which reflected the unique responsiveness of the gel system. Through these two key parts, we hope to provide useful insights into the design and control of functional nanoarchitectures via supramolecular gelation.

中文翻译:

通过超分子凝胶化的纳米建筑学:各种纳米结构的形成和转换

目前,超分子凝胶是一类重要的柔软材料,引起了人们的极大兴趣。胶凝过程已被证明是用于构建多样化和统一体系结构的强大方法。通常,这些体系结构是纳米级的,由小分子分层自组装而成。纳米建筑学试图弥合分子与纳米结构之间的鸿沟,而超分子凝胶化为实现这一目标提供了一个良好的平台。虽然胶凝剂分子的设计和凝胶的功能是重要的话题,但在这里,我们关注的是如何通过胶凝将小分子制造成纳米结构,这实际上是微观结构与宏观功能之间的联系。我们展示了通过超分子凝胶化过程构建的典型架构的优异实例。然后给出了一些实例,这些实例显示了不同纳米结构之间的转化或转换,这反映了凝胶系统的独特响应性。通过这两个关键部分,我们希望对功能纳米体系结构的设计和控制提供有用的见解。通过超分子凝胶化。
更新日期:2018-10-25
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