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Effects of sonication on photocatalytic reforming of aqueous glycerol solution
Ultrasonics Sonochemistry ( IF 8.4 ) Pub Date : 2018-10-22 , DOI: 10.1016/j.ultsonch.2018.10.027
Y. Mizukoshi

Large amount of glycerol has been generated as a byproduct in the synthesis of biodiesel fuel and their effective utilization ways have been explored. Addition of glycerol effectively enhanced photocatalytic H2 evolution from aqueous solution dispersing TiO2 photocatalyst nanoparticles. The deuterium labeled experiments clarified that noticeable amount of hydrogen atoms are supplied from glycerol molecules. H2 and CO2 were mainly evolved under UV illumination. On the other hand, sonication to the UV-illuminated system enhanced the CO evolution and the amount of the evolved CO depended upon the intensity of the ultrasound. Sonochemical modulation of H2/CO ratio is a promising approach to produce syngas, which is an important raw material in C1 chemistry.



中文翻译:

超声处理对甘油水溶液光催化重整的影响

在合成生物柴油燃料中已产生大量副产物甘油,并探索了它们的有效利用方式。甘油的添加有效地增强了从分散TiO 2光催化剂纳米颗粒的水溶液中光催化H 2的释放。氘标记的实验表明,甘油分子提供了大量的氢原子。H 2和CO 2主要在紫外线照射下放出。另一方面,对紫外线照射的系统进行超声处理会增强CO的释放,并且所释放的CO的量取决于超声的强度。H 2的声化学调制/ CO比是生产合成气的一种有前途的方法,合成气是C1化学中的重要原料。

更新日期:2019-03-12
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