Front Cover: Postfunctionalization of Tris(pyridyl) Aluminate Ligands: Chirality, Coordination, and Supramolecular Chemistry (Chem. Eur. J. 64/2018),Chemistry - A European Journal

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Front Cover: Postfunctionalization of Tris(pyridyl) Aluminate Ligands: Chirality, Coordination, and Supramolecular Chemistry (Chem. Eur. J. 64/2018)
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2018-10-18 , DOI: 10.1002/chem.201804886
Álvaro García‐Romero ₁ , Alex J. Plajer ₂ , Lucía Álvarez‐Miguel ₁ , Andrew D. Bond ₂ , Dominic S. Wright ₂ , Raúl García‐Rodríguez ₁

Affiliation

A Chiral‐at‐Al aluminate can be prepared by the stepwise reaction of two different alcohols with the aluminate anion [EtAl(6‐Me‐2‐py)₃]⁻. The method can also be used to prepare chiral‐at‐ligand aluminates and for the introduction of 3‐py and 4‐py functionalities into the aluminate framework through the selective and controlled substitution of one or two pyridine arms, thereby giving entry to new supramolecular chemistry. The cover represents the formation of such a rare example of a chiral‐at‐aluminum aluminate and it is also a tribute to the oneiric worlds of surrealist painter René Magritte. More information can be found in the Full Paper by R. García‐Rodríguez et al. on page 17019.

中文翻译：

封面：三（吡啶基）铝酸盐配体的后功能化：手性，配位和超分子化学（Eur.J.64 / 2018）

可以通过两种不同的醇与铝酸盐阴离子[EtAl（6-Me-2-py）₃ ] ^-的逐步反应来制备手性铝酸盐。该方法还可用于制备手性配位铝酸盐，并通过选择性或可控地取代一个或两个吡啶臂，将3 py和4 py官能团引入铝酸盐骨架中，从而使新的超分子化合物进入市场化学。封面代表了这种罕见的手性铝铝酸盐实例的形成，同时也向超现实主义画家勒内·马格利特（RenéMagritte）的怪诞世界致敬。更多信息可以在R.García-Rodríguez等人的论文全文中找到。在第17019页。

更新日期：2018-10-18

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