Interaction of an imidazolium-2-amidinate (NHC-CDI) zwitterion with zinc dichloride in dichloromethane: role as ligands and C–Cl activation promoters†‡,Chemical Communications

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Interaction of an imidazolium-2-amidinate (NHC-CDI) zwitterion with zinc dichloride in dichloromethane: role as ligands and C–Cl activation promoters†‡
Chemical Communications ( IF 4.9 ) Pub Date : 2018-10-17 00:00:00 , DOI: 10.1039/c8cc07661h
David Sánchez-Roa _{1,

2,

3,

4,

5} , Tomás G. Santiago _{5,

6,

7,

8} , Maria Fernández-Millán _{1,

2,

3,

4,

5} , Tomás Cuenca _{1,

2,

3,

4,

5} , Pilar Palma _{5,

6,

7,

8} , Juan Cámpora _{5,

6,

7,

8} , Marta E. G. Mosquera _{1,

2,

3,

4,

5}

Affiliation

Adducts of imidazolium carbenes and carbodiimides (NHC-CDI) are emerging as a new class of thermally stable and modular zwitterions with many potential applications. Our study of the interaction of a representative NHC-CDI zwitterion with ZnCl₂ in dichloromethane led to the serendipitous discovery of a highly selective, double activation of dichloromethane C–Cl bonds.

中文翻译：

咪唑-2-脒（NHC-CDI）的相互作用两性离子与锌二氯化二氯甲烷：作为配体和C-CL激活的启动子的作用†往最 ‡

咪唑鎓卡宾和碳二亚胺（NHC-CDI）的加合物正在发展成为一类新型的热稳定和模块化两性离子，具有许多潜在应用。我们对代表性的NHC-CDI两性离子与ZnCl ₂在二氯甲烷中的相互作用的研究导致偶然发现了高选择性的，双重激活的二氯甲烷C-Cl键。

更新日期：2018-10-17

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