Structural effects of ditopic azoprobe–cyclodextrin complexes on the selectivity of guest-induced supramolecular chirality,Chemical Communications

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Structural effects of ditopic azoprobe–cyclodextrin complexes on the selectivity of guest-induced supramolecular chirality
Chemical Communications ( IF 4.3 ) Pub Date : 2018-10-17 , DOI: 10.1039/c8cc02242a
Shoji Fujiwara _{1,

2,

3,

4,

5} , Kentaro Nonaka _{5,

6,

7,

8,

9} , Mai Yamaguchi _{5,

6,

7,

8,

9} , Takeshi Hashimoto _{5,

6,

7,

8,

9} , Takashi Hayashita _{5,

6,

7,

8,

9}

Affiliation

Benzo-15-crown-5 and dipicolylamine are contained as the binding sites in a ditopic azoprobe (15C5-Azo-n-dpa). However, the selectivities of guest-induced supramolecular chirality for cations and anions were dramatically altered by a slight change in the spacer length of (15C5-Azo-n-dpa)₂–γ-CyD complexes in water.

中文翻译：

偶氮偶氮唑-环糊精配合物的结构效应对客体诱导的超分子手性的选择性

Benzo-15-crown-5和二聚烯丙基胺作为结合位点包含在对位偶氮唑（15C5-Azo- n -dpa）中。然而，客体诱导的超分子手性对阳离子和阴离子的选择性由于水中（15C5-Azo- n -dpa）₂ -γ -CyD配合物的间隔长度的微小变化而显着改变。

更新日期：2018-11-08

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