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Enhancement of the quality of syngas from catalytic steam gasification of biomass by the addition of methane/model biogas
International Journal of Hydrogen Energy ( IF 8.1 ) Pub Date : 2018-10-17 , DOI: 10.1016/j.ijhydene.2018.09.068
Yalan Shen , Yang Liu , Haimiao Yu

In this study, methane and model biogas were added during the catalytic steam gasification of pine to regulate the syngas composition and improve the quality of syngas. The effects of Ni/γ-Al2O3 catalyst, steam and methane/model biogas on H2/CO ratio, syngas yield, carbon conversion rate and tar yield were explored. The results indicated that the addition of methane/model biogas during biomass steam gasification could increase the H2/CO ratio to about 2. Methane/model biogas, steam and Ni/γ-Al2O3 catalyst significantly affected the quality of syngas. High H2 content syngas with H2/CO ratio of about 2, biomass carbon conversion >85% and low tar yield was achieved under the optimum condition: S/C = 1.5, α = 0.2 and using Ni/γ-Al2O3 catalyst. According to ANOVA, methane and catalyst were the key influencing factors of the H2/CO ratio and syngas yield, and the tar yield mainly depended on the Ni/γ-Al2O3 catalyst. Biogas, as a more environmentally friendly material than methane, can also regulate the composition of syngas co-feeding with biomass.



中文翻译:

通过添加甲烷/模型沼气,提高生物质催化蒸汽气化合成气的质量

在这项研究中,在松木的催化蒸汽气化过程中添加了甲烷和模型沼气,以调节合成气的组成并提高合成气的质量。的Ni /γ-Al的影响2 ö 3催化剂,蒸汽,而H甲烷/模型沼气2 / CO比,合成气产量,碳转化率和焦油量进行了探讨。结果表明生物质蒸汽气化过程中加入甲烷/模型沼气可以增加为H 2 / CO比至约2。甲烷/模型沼气,蒸汽和Ni /γ-Al系2 ö 3催化剂显著影响合成气的质量。高H 2含量的合成气与H 2约2 / CO比,生物质的碳转化> 85%和低焦油产率的最佳条件下实现的:S / C  = 1.5,α  = 0.2和用Ni /γ-Al系2 ö 3催化剂。根据ANOVA,甲烷和催化剂是主要影响的H因子2和/ CO比的合成气产量,和焦油产率主要取决于在Ni /γ-Al系2 ö 3催化剂。沼气作为一种比甲烷更环保的材料,也可以调节与生物质共同进料的合成气的组成。

更新日期:2018-10-17
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