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Effect of NiO impurity on the magneto-transport properties of the La0.7Ba0.3MnO3 granular manganite
Chemical Physics Letters ( IF 2.8 ) Pub Date : 2018-10-17 , DOI: 10.1016/j.cplett.2018.10.040
Abd El-Moez A. Mohamed , Aml M. Mohamed , A. ElShafaie , H.F. Mohamed , A.K. Diab , A.M. Ahmed

Magnetoresistive, magnetic and thermoelectric properties of the La0.7Ba0.3MnO3/xNiO system are studied. The x-ray diffraction shows the coexistence of the NiO and the La0.7Ba0.3MnO3 phases in doped composites, revealing their interaction lack. This suggests the precipitation of the NiO at grain boundaries and on the La0.7Ba0.3MnO3 surface, interrupting the conduction between grains. Hindering the direct contact between the La0.7Ba0.3MnO3 grains increases the resistivity and decreases the metal-semiconductor transition temperature, leading to the spin tunneling effect. This enhances the room temperature magnetoresistance of the La0.7Ba0.3MnO3 compound from -11.25% to -42.7% and -17.24% for 5% and 20% of the NiO additive amount, respectively. The pristine La0.7Ba0.3MnO3 compound shows a Curie temperature value of 348K that fluctuates negligibly with the NiO addition. However, it decreases to 332K in the x=0.05 composite due to a tiny diffusion of NiO in the La0.7Ba0.3MnO3 lattice at this composite. The thermoelectric power properties of the La0.7Ba0.3MnO3 compound are changed with the NiO addition. Where the hole conduction interval increases and the peak of Seebeck coefficient is shifted towards higher temperatures.



中文翻译:

NiO杂质对La 0.7 Ba 0.3 MnO 3颗粒锰矿磁传输性能的影响

研究了La 0.7 Ba 0.3 MnO 3 / x NiO体系的磁阻,磁和热电性质。X射线衍射显示掺杂复合材料中NiO和La 0.7 Ba 0.3 MnO 3相共存,表明它们之间没有相互作用。这表明NiO在晶界和La 0.7 Ba 0.3 MnO 3表面上的沉淀,中断了晶粒之间的导电。阻碍La 0.7 Ba 0.3 MnO 3之间的直接接触晶粒增加电阻率并降低金属-半导体的转变温度,从而导致自旋隧穿效应。对于NiO添加量的5%和20%,这将La 0.7 Ba 0.3 MnO 3化合物的室温磁阻分别从-11.25%提高到-42.7%和-17.24%。原始的La 0.7 Ba 0.3 MnO 3化合物的居里温度值为348K,随添加NiO的变化可忽略不计。但是,由于NiO在La 0.7 Ba 0.3 MnO 3中的微小扩散,在x = 0.05复合材料中它减少到332K此复合材料上的晶格。La 0.7 Ba 0. 3MnO3化合物的热电性能随NiO的添加而变化。空穴传导间隔增加并且塞贝克系数的峰值移向更高的温度。

更新日期:2018-10-17
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