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Hybrid Solid Polymer Electrolytes with Two‐Dimensional Inorganic Nanofillers
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2018-11-20 , DOI: 10.1002/chem.201804781
Stephanie Chua 1 , Ruopian Fang 2 , Zhenhua Sun 2 , Minjie Wu 2 , Zi Gu 1 , Yuzuo Wang 2 , Judy N. Hart 3 , Neeraj Sharma 4 , Feng Li 2 , Da‐Wei Wang 1
Affiliation  

Solid polymer electrolytes are of rapidly increasing importance for the research and development of future safe batteries with high energy density. The diversified chemistry and structures of polymers allow the utilization of a wide range of soft structures for all‐polymer solid‐state electrolytes. With equal importance is the hybrid solid‐state electrolytes consisting of both “soft” polymeric structure and “hard” inorganic nanofillers. The recent emergence of the re‐discovery of many two‐dimensional layered materials has stimulated the booming of advanced research in energy storage fields, such as batteries, supercapacitors, and fuel cells. Of special interest is the mass transport properties of these 2D nanostructures for water, gas, or ions. This review aims at the current progress and prospective development of hybrid polymer‐inorganic solid electrolytes based on important 2D materials, including natural clay and synthetic lamellar structures. The ion conduction mechanism and the fabrication, property and device performance of these hybrid solid electrolytes will be discussed.

中文翻译:

带有二维无机纳米填料的杂化固体聚合物电解质

固体聚合物电解质对于未来具有高能量密度的安全电池的研究和开发具有越来越重要的意义。聚合物的多样化化学和结构允许对全聚合物固态电解质使用各种软结构。同样重要的是由“软”聚合物结构和“硬”无机纳米填料组成的混合固态电解质。最近发现的许多二维分层材料的兴起刺激了诸如电池,超级电容器和燃料电池等储能领域的高级研究的蓬勃发展。这些二维纳米结构对水,气体或离子的传质特性特别受关注。这篇综述针对基于重要的2D材料(包括天然粘土和合成层状结构)的混合聚合物-无机固体电解质的最新进展和未来发展。将讨论这些杂化固体电解质的离子传导机理以及制造,性能和器件性能。
更新日期:2018-11-20
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