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Isolation of inorganic molecular chains from rod-like bulk V2Se9 crystal by liquid exfoliation
RSC Advances ( IF 3.9 ) Pub Date : 2018-10-15 00:00:00 , DOI: 10.1039/c8ra06975a
Sudong Chae 1 , Akhtar J Siddiqa 1 , Bum Jun Kim 2 , Seungbae Oh 1 , Kyung Hwan Choi 2 , Keun Ho Lee 1 , Hyo Yeol Kim 1 , Hak Ki Yu 3 , Jae-Young Choi 1, 2
Affiliation  

We studied the optimum dispersion solvent for bulk V2Se9 material, which can be used as a new one-dimensional (1D) material, to separate into 1D chain units. Selected twelve solvents, which have different dielectric constants and surface tensions, were tested to exfoliate bulk V2Se9 into nano-scale chains. The atomic level (∼1 nm, mono-chain) exfoliation of V2Se9 was performed using acetone as the solvent. The dispersion concentration was high in solvents having medium dielectric constants ranging from 20 to 40 with surface tensions ranging from 25 to 35 mJ m−2. This result is similar to the dispersion results of previous transition metal dichalcogenides (TMDCs) such as MoS2, WS2, MoSe2, MoTe2, TaSe2, NbSe2, and NiTe2, indicating that the V2Se9 material and its dispersion to 1D units can be expected to play an important role in opening opportunities for new low-dimensional material studies.

中文翻译:

液体剥离法从棒状块状 V2Se9 晶体中分离无机分子链

我们研究了散装V 2 Se 9材料的最佳分散溶剂,该材料可作为一种新的一维(1D)材料分离成一维链单元。测试了选择的十二种具有不同介电常数和表面张力的溶剂,以将块状 V 2 Se 9剥离成纳米级链。使用丙酮作为溶剂进行V 2 Se 9的原子级(~1 nm,单链)剥离。在具有 20 至 40 的中等介电常数和 25 至 35 mJ m -2的表面张力的溶剂中,分散体浓度很高. 该结果与以往的MoS 2、WS 2、MoSe 2、MoTe 2、TaSe 2、NbSe 2、 NiTe 2等过渡金属二硫属化物(TMDCs)的色散结果相似,表明V 2 Se 9材料及其预计分散到一维单位将在开辟新的低维材料研究机会方面发挥重要作用。
更新日期:2018-10-15
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