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Naphthyl substituted triphenylamine derivatives as hole transporting materials for efficient red PhOLEDs
Dyes and Pigments ( IF 4.1 ) Pub Date : 2018-10-16 , DOI: 10.1016/j.dyepig.2018.10.020
Gintare Krucaite , Dmytro Volyniuk , Jurate Simokaitiene , Saulius Grigalevicius , Chun-Han Lin , Chang-Min Shao , Chih-Hao Chang

Naphthyl substituted triphenylamine and its derivatives with bromine atoms were synthesized and investigated. The respective glass transition temperatures of the materials were estimated to be in a range 65–137 °C, which can provide morphologically-stable amorphous films for applications in organic light emitting diodes. The compounds possess adequate ionization potentials (5.5–5.75 eV), high hole drift mobilities (>10−3 cm2/V·s) and suitable triplet energies (∼2.4 eV), which make them suitable hole transporting materials for use in red phosphorescent organic light-emitting diodes. A superior peak efficiency of 17.9% (31.4 cd/A and 26.9 lm/W) was achieved in a device having hole transporting layer of tris[4-(1-naphthyl)phenyl]amine. Furthermore, the device gave efficiencies of 17.7% and 16.6% recorded at luminance levels of 102 and 103 cd/m2. The efficiency drop from the maximum to the value recorded at the luminance of 103 cd/m2 for the device was only 7%.



中文翻译:

萘基取代的三苯胺衍生物作为高效红色PhOLED的空穴传输材料

合成并研究了萘基取代的三苯胺及其具有溴原子的衍生物。估计材料的各自玻璃化转变温度在65–137°C的范围内,可以为有机发光二极管提供形态稳定的非晶膜。这些化合物具有足够的电离势(5.5–5.75 eV),高空穴迁移率(> 10 -3 cm 2/ V·s)和合适的三重态能量(〜2.4 eV),这使其成为适用于红色磷光有机发光二极管的空穴传输材料。在具有三[4-(1-萘基)苯基]胺的空穴传输层的器件中,获得了17.9%(31.4 cd / A和26.9 lm / W)的出色峰值效率。此外,该装置在10 2和10 3  cd / m 2的亮度水平下记录的效率为17.7%和16.6%。该器件的效率从最大值下降到以10 3  cd / m 2的亮度记录的值仅为7%。

更新日期:2018-10-16
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