Increasing the nuclearity and spin ground state in a new family of ferromagnetically-coupled {Ni10} disk-like complexes bearing exclusively end-on bridging azido ligands†,Chemical Communications

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Increasing the nuclearity and spin ground state in a new family of ferromagnetically-coupled {Ni10} disk-like complexes bearing exclusively end-on bridging azido ligands†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-10-15 00:00:00 , DOI: 10.1039/c8cc07722c
Jasmin Krause _{1,

2,

3,

4} , Dimitris I. Alexandropoulos _{5,

6,

7} , Luca M. Carrella _{1,

2,

3,

4} , Eva Rentschler _{1,

2,

3,

4} , Theocharis C. Stamatatos _{1,

2,

3,

4,

5}

Affiliation

The synthesis of a new family of ferromagnetically-coupled {Ni₁₀} clusters counterbalanced by various [Ln(NO₃)₅]²⁻ ions is herein described. The resulting compounds are organic chelate-free and the metal ions are exclusively bridged by end-on azido ligands to stabilize a beautiful disk-like topology reminiscent of the structure of the brucite mineral.

中文翻译：

在新的铁磁耦合{Ni ₁₀ }盘状复合物家族中，仅带有末端桥联叠氮基配体的核和自旋基态†

本文描述了由各种[Ln（NO ₃）₅ ] ^2-离子平衡的新的铁磁耦合{Ni ₁₀ }团簇的合成。所得化合物不含有机螯合物，金属离子仅通过端基叠氮基配体桥接，以稳定美丽的盘状拓扑，让人联想起水镁石矿物的结构。

更新日期：2018-10-15

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