From Mononuclear Complexes to Molecular Nanoparticles: The Buildup of Atomically Precise Heterometallic Rhodium Carbonyl Nanoclusters,Accounts of Chemical Research

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From Mononuclear Complexes to Molecular Nanoparticles: The Buildup of Atomically Precise Heterometallic Rhodium Carbonyl Nanoclusters
Accounts of Chemical Research ( IF 16.4 ) Pub Date : 2018-10-12 00:00:00 , DOI: 10.1021/acs.accounts.8b00354
Cristina Femoni ₁ , Maria Carmela Iapalucci ₁ , Silvia Ruggieri ₁ , Stefano Zacchini ₁

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Chemical research in synthesizing metal nanoparticles has been a major topic in the last two decades, as nanoparticles can be of great interest in many fields such as biology, catalysis, and nanotechnology. However, as their chemical and physical properties are size-dependent, the reliable preparation of nanoparticles at a molecular level is highly desirable. Despite the remarkable advances in recent years in the preparation of thiolate- or p-MBA or PA-protected gold and silver nanoclusters (p-MBA = p-mercaptobenzoic acid; PA = phenylalkynyl), as well as the large palladium clusters protected by carbonyl and phosphine ligands that initially dominated the field, the synthesis of monodispersed and atomically precise nanoparticles still represents a great challenge for chemists.

中文翻译：

从单核络合物到分子纳米颗粒：原子精确的杂金属铑羰基纳米簇的建立

在过去的二十年中，合成金属纳米粒子的化学研究一直是一个主要课题，因为纳米粒子在生物学，催化和纳米技术等许多领域都引起了极大的兴趣。然而，由于它们的化学和物理性质取决于尺寸，因此非常需要在分子水平上可靠地制备纳米颗粒。尽管近年来在制备硫醇盐或p- MBA或PA保护的金和银纳米簇方面取得了显着进展（p- MBA = p-巯基苯甲酸；PA =苯基炔基），以及最初主导该领域的受羰基和膦配体保护的大型钯簇，单分散且原子精确的纳米颗粒的合成仍对化学家构成巨大挑战。

更新日期：2018-10-12

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