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An alternative stereoselective synthesis of greensporone C
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2018-10-12 , DOI: 10.1016/j.tetlet.2018.10.020
Venkata Naresh Vema , Y. Bharathi kumari , Sridhar Musulla , RamaKrishnam Raju Addada , Srinivasa Rao Alapati

Greensporone C, a new 14-membered resorcylic acid lactone, has been synthesized from inexpensive and commercially available starting materials. This convergent synthesis utilizes Cross metathesis using the Grubbs Hoveyda catalyst, alkylation of 1,3-dithiane and Yamaguchi macrolactonization as key steps.



中文翻译:

Greensporone C的另一种立体选择性合成

Greensporone C是一种新型的14元间苯二酸内酯,它是由廉价且可商购的起始原料合成的。该聚合合成利用了使用Grubbs Hoveyda催化剂的交叉复分解,1,3-二硫代烷基的烷基化和山口大内酯化作为关键步骤。

更新日期:2018-10-12
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