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The Domino Hexadehydro-Diels-Alder Reaction: An Elegant Way toward Polyacenes
Chem ( IF 23.5 ) Pub Date : 2018-10-11 , DOI: 10.1016/j.chempr.2018.09.021
Yann Trolez

Recently in Nature Chemistry, Xiao and Hoye showed that it is possible to use hexadehydro-Diels-Alder (HDDA) reactions in a domino process to access functionalized polyacenes in high yields. They employed up to four consecutive HDDA reactions to build new highly conjugated polyaromatic molecules.



中文翻译:

多米诺六氢-狄尔斯-阿尔德反应:制备聚苯的一种优雅方法

Xiao和Hoye最近在《自然化学》杂志上表明,可以在多米诺骨牌工艺中使用六氢-狄尔斯-阿尔德(HDDA)反应,以高产率获得官能化的聚并苯。他们采用了多达四个连续的HDDA反应来构建新的高度共轭的多芳族分子。

更新日期:2018-10-11
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