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Reversible deactivation of γ-alumina by steam in the gas-phase dehydration of methanol to dimethyl ether
Catalysis Communications ( IF 3.4 ) Pub Date : 2018-10-10 , DOI: 10.1016/j.catcom.2018.10.008
Jurriaan Boon , Jasper van Kampen , Roelof Hoogendoorn , Stefania Tanase , Frans P.F. van Berkel , Martin van Sint Annaland

Acidic γ-Al2O3 is an active catalyst for the dehydration of methanol to dimethyl ether (DME). However, the produced steam reduces the activity. In this work, the influence of the exposure of γ-Al2O3 to steam on the catalytic activity for methanol dehydration has been determined. At 250 °C and increasing stream partial pressure the conversion of γ-Al2O3 into γ-AlO(OH) is observed at a p(H2O) of 13–14 bar. As a consequence, the catalytic activity decreases, reducing the rate of methanol dehydration to around 25%. However, this conversion is reversible and under reaction conditions γ-AlO(OH) converts back to γ-Al2O3, recovering its catalytic activity.



中文翻译:

甲醇气相脱水制二甲醚中的水蒸气可逆失活γ-氧化铝

酸性的γ-Al 2 ö 3是用于甲醇脱水为二甲醚(DME)的活性催化剂。但是,产生的蒸汽降低了活性。在这项工作中,γ-Al系的曝光的影响2 Ò 3对用于甲醇脱水催化剂的活性蒸汽已被确定。在250℃下和增加流分压的γ-Al的转化2 ö 3成γ-的AlO(OH)在AP(H观察到2 O)的13-14巴。结果,催化活性降低,甲醇脱水率降低到约25%。但是,这种转换是可逆的,并且在反应条件γ-的AlO(OH)转换回的γ-Al 2 ö 3,恢复其催化活性。

更新日期:2018-10-10
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