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Induced Aggregation and Synergistic Coordination Strategy in Cluster Organic Architectures
Accounts of Chemical Research ( IF 16.4 ) Pub Date : 2018-10-09 00:00:00 , DOI: 10.1021/acs.accounts.8b00346 Wei-Hui Fang 1, 2 , Guo-Yu Yang 1
Accounts of Chemical Research ( IF 16.4 ) Pub Date : 2018-10-09 00:00:00 , DOI: 10.1021/acs.accounts.8b00346 Wei-Hui Fang 1, 2 , Guo-Yu Yang 1
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Developments in strategies for the synthesis of oxo–hydroxo lanthanide (Ln) clusters during the past few decades have resulted in abundant relevant crystalline materials that exhibit attractive structures and interesting properties. The combination of these oxo–hydroxo Ln clusters and organic ligands has led to the formation of new extended arrays of Ln cluster organic frameworks (LnCOFs). In contrast to metal–organic frameworks, the incorporation of particular characteristics of clusters provides the opportunity to develop performances not available in single-metal compounds. Even with steady advances in oxo–hydroxo Ln clusters, progress in LnCOFs is less developed.
中文翻译：
集群有机体系结构中的诱导聚合和协同协调策略
在过去的几十年中，合成氧-羟基镧系元素（Ln）的策略的发展已导致大量相关的晶体材料呈现出诱人的结构和令人感兴趣的特性。这些氧-羟基Ln团簇和有机配体的结合导致形成了新的Ln团簇有机骨架（LnCOFs）扩展阵列。与金属有机框架相反，团簇特殊特征的结合提供了发展单金属化合物所不具备的性能的机会。即使氧-羟基Ln团簇稳步发展，LnCOFs的进展仍很少。
更新日期：2018-10-09
中文翻译：
集群有机体系结构中的诱导聚合和协同协调策略
在过去的几十年中，合成氧-羟基镧系元素（Ln）的策略的发展已导致大量相关的晶体材料呈现出诱人的结构和令人感兴趣的特性。这些氧-羟基Ln团簇和有机配体的结合导致形成了新的Ln团簇有机骨架（LnCOFs）扩展阵列。与金属有机框架相反，团簇特殊特征的结合提供了发展单金属化合物所不具备的性能的机会。即使氧-羟基Ln团簇稳步发展，LnCOFs的进展仍很少。
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