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Molecular Bottlebrushes as Novel Materials.
Biomacromolecules ( IF 5.5 ) Pub Date : 2018-10-22 , DOI: 10.1021/acs.biomac.8b01171
Guojun Xie 1 , Michael R Martinez 1 , Mateusz Olszewski 1 , Sergei S Sheiko 2 , Krzysztof Matyjaszewski 1
Affiliation  

Molecular bottlebrushes are building blocks for the design of unique polymeric materials whose physical properties are fundamentally governed by their densely grafted structures. Recent developments in the area of reversible deactivation radical polymerization enabled facile and effective control over multiple molecular parameters. Owing to large molecular size, anisotropic conformation, and reduced chain entanglement, molecular bottlebrushes have empowered various applications that are challenging to achieve with linear polymers. In this Review, we focus on determining correlations between brushlike architectures and materials properties.

中文翻译:

分子瓶刷作为新型材料。

分子瓶刷是设计独特聚合物材料的基础,其物理性能从根本上受其密集的接枝结构支配。可逆失活自由基聚合领域的最新发展使得能够轻松有效地控制多个分子参数。由于分子尺寸大,各向异性的构型和减少的链缠结,分子刷已经赋予了各种应用带来的挑战,而线性聚合物很难实现这些应用。在这篇评论中,我们着重于确定类似画笔的体系结构和材料属性之间的相关性。
更新日期:2018-10-08
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