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Facile synthesis of flower-like morphology Cu0.27Co2.73O4 for a high-performance supercapattery with extraordinary cycling stability†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-10-05 00:00:00 , DOI: 10.1039/c8cc04625e
Shipra Raj 1, 2, 3, 4 , Pradip Kar 1, 2, 3, 4 , Poulomi Roy 4, 5, 6, 7, 8
Affiliation  

The partial replacement of Co by Cu in cobaltite to give Cu0.27Co2.73O4 with unique flower-like morphology is found to be very beneficial for supercapacitor–battery hybrid applications. The 3D architecture of the material on a conductive substrate resulted in outstanding supercapattery performance. Asymmetric assembly of the material with activated carbon in a two-electrode system delivered high energy and power densities as well as a high specific capacity. The device also showed excellent cycling stability over 20 000 cycles, with a capacity retention value of 86.9%.

中文翻译:

花状形态Cu 0.27 Co 2.73 O 4的简便合成,可实现具有出色循环稳定性的高性能超级电池

研究发现,钴粉中的铜部分取代Co可以得到具有独特花状形态的Cu 0.27 Co 2.73 O 4,这对超级电容器-电池混合应用非常有利。导电基板上材料的3D体系结构带来了出色的超级电容性能。该材料与活性炭在两电极系统中的不对称组装提供了高能量和功率密度以及高比容量。该器件还显示了超过20000次循环的出色循环稳定性,容量保持值为86.9%。
更新日期:2018-10-05
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