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Large-scale converting waste coffee grounds into functional carbon materials as high-efficient adsorbent for organic dyes
Bioresource Technology ( IF 9.7 ) Pub Date : 2018-10-05 , DOI: 10.1016/j.biortech.2018.10.011
Xin Wen , Hansong Liu , Lu Zhang , Jing Zhang , Can Fu , Xiaoze Shi , Xuecheng Chen , Ewa Mijowska , Ming-Jun Chen , De-Yi Wang

Functional carbon materials have been fabricated through simple and effective catalytic carbonization with waste coffee grounds (CGs) as carbon precursor and FeCl3 as catalyst. The effect of FeCl3 loading and carbonization temperature on carbon yield was investigated. The morphology and structure of as-synthesized carbons was characterized by scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray diffraction (XRD), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS) and nitrogen isothermal adsorption/desorption measurement, respectively. Furthermore, the carbon materials showed high efficiency for the removal of methylene blue (MB, 653.6 mg g−1), methyl orange (MO, 465.8 mg g−1) and rhodamine B (RB, 366.1 mg g−1). More importantly, the carbon was magnetic, so it can be easily separated by a magnet and reused multiple times. This work not only exploited a low–cost and large-scale preparation method to synthesize functional carbon materials from bioresources, but also provided an eco-friendly and effective adsorbent in water purification applications.



中文翻译:

大规模将废咖啡渣转化为功能性碳材料,作为有机染料的高效吸附剂

通过使用废咖啡渣(CGs)作为碳前驱体和FeCl 3作为催化剂,通过简单有效的催化碳化来制造功能性碳材料。研究了FeCl 3的添加量和碳化温度对碳收率的影响。通过扫描电子显微镜(SEM),透射电子显微镜(TEM),X射线衍射(XRD),拉曼光谱,X射线光电子能谱(XPS)和氮等温吸附/解吸测量。此外,碳材料显示出高效率的亚甲基蓝(MB,653.6 mg g -1),甲基橙(MO,465.8 mg g -1)的去除。)和若丹明B(RB,366.1 mg g -1)。更重要的是,碳是磁性的,因此可以很容易地被磁铁分开并重复使用多次。这项工作不仅利用低成本,大规模的制备方法来从生物资源中合成功能性碳材料,而且还为净水应用提供了一种环保,有效的吸附剂。

更新日期:2018-10-05
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