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New developments in liquid-liquid extraction, surface modification and agglomerate-free processing of inorganic particles
Advances in Colloid and Interface Science ( IF 15.9 ) Pub Date : 2018-09-27 , DOI: 10.1016/j.cis.2018.09.005
R.M.E. Silva , R. Poon , J. Milne , A. Syed , I. Zhitomirsky

This review describes new methods for the particle extraction through liquid-liquid interface (PELLI). The discovery of new surface modification techniques, advanced extractors and new adsorption mechanisms enabled novel applications of PELLI in nanotechnology of metals, quantum dots, oxides and hydroxides. Colloidal and interface chemistry of PELLI is emerging as a new area of technological and scientific interest. The progress achieved in the understanding of particle behavior and interactions at the liquid-liquid interface, phase transfer and interface reactions allowed for the development of new extraction mechanisms. An important breakthrough was the development of surface modification techniques for extraction of functional oxides. Especially important is the possibility of particle transfer from the synthesis medium to the device processing medium, which facilitates agglomerate-free processing of functional nanoparticles. Multifunctional extractor molecules were discovered and used as capping and reducing agents for particle synthesis or dispersing and charging agents for colloidal processing. The progress achieved in the development of extractors and extraction mechanisms has driven the advances in the surface modification and functionalization of materials. New PELLI techniques were used for the development of advanced materials and devices for optical, photovoltaic, energy storage, electronic, biomedical, sensor and other applications.



中文翻译:

液-液萃取,表面改性和无团聚处理无机颗粒的新进展

这篇综述描述了通过液-液界面(PELLI)进行颗粒提取的新方法。新的表面改性技术,先进的萃取器和新的吸附机制的发现使PELLI在金属,量子点,氧化物和氢氧化物的纳米技术中有了新的应用。PELLI的胶体和界面化学正在成为技术和科学兴趣的新领域。在理解颗粒行为和在液-液界面处的相互作用,相转移和界面反应方面取得的进展允许开发新的萃取机理。一个重要的突破是用于提取功能性氧化物的表面改性技术的发展。颗粒从合成介质转移到设备处理介质的可能性尤其重要,这有助于功能性纳米颗粒的无团聚处理。发现了多功能萃取剂分子,并将其用作用于颗粒合成的封端剂和还原剂,或用作胶体加工的分散剂和带电剂。萃取器和萃取机构的开发取得了进展,推动了材料的表面改性和功能化的发展。新的PELLI技术用于开发先进的材料和设备,用于光学,光伏,能量存储,电子,生物医学,传感器和其他应用。发现了多功能萃取剂分子,并将其用作用于颗粒合成的封端剂和还原剂,或用作胶体加工的分散剂和带电剂。萃取器和萃取机构的开发取得了进展,推动了材料的表面改性和功能化的发展。新的PELLI技术用于开发先进的材料和设备,用于光学,光伏,能量存储,电子,生物医学,传感器和其他应用。发现了多功能萃取剂分子,并将其用作用于颗粒合成的封端剂和还原剂,或用作胶体加工的分散剂和带电剂。萃取器和萃取机构的开发取得了进展,推动了材料的表面改性和功能化的发展。新的PELLI技术用于开发先进的材料和设备,用于光学,光伏,能量存储,电子,生物医学,传感器和其他应用。

更新日期:2018-09-28
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