Synthesis of (+)-altholactone, (+)-7-epi-altholactone, (−)-etharvensin, and (+)-alumheptolide-A using Pd-catalyzed carbonylation,Tetrahedron Letters

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Synthesis of (+)-altholactone, (+)-7-epi-altholactone, (−)-etharvensin, and (+)-alumheptolide-A using Pd-catalyzed carbonylation
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2018-09-26 , DOI: 10.1016/j.tetlet.2018.09.062
Yuki Miyazawa , Yasunao Hattori , Hidefumi Makabe

Syntheses of (+)-altholactone isolated from Goniothalamus giganteus and its C-7 epimer (+)-7-epi-altholactone, (−)-etharvensin and (+)-alumheptolide-A were achieved. The lactone ring of these compounds was constructed using Pd-catalyzed carbonylation.

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