Methanol as hydrogen source: transfer hydrogenation of aromatic aldehydes with a rhodacycle†,Chemical Communications

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Methanol as hydrogen source: transfer hydrogenation of aromatic aldehydes with a rhodacycle†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-09-26 00:00:00 , DOI: 10.1039/c8cc06612d
Ahmed H. Aboo _{1,

2,

3} , Elliot L. Bennett _{1,

2,

3} , Mark Deeprose _{1,

2,

3} , Craig M. Robertson _{1,

2,

3} , Jonathan A. Iggo _{1,

2,

3} , Jianliang Xiao _{1,

2,

3}

Affiliation

A cyclometalated rhodium complex has been shown to perform highly selective and efficient reduction of aldehydes, deriving the hydrogen from methanol. With methanol as both the solvent and hydrogen donor under mild conditions and an open atmosphere, a wide range of aromatic aldehydes were reduced to the corresponding alcohols, without affecting other functional groups.

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