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C60-assisted crystal engineering for perovskite solar cells with enhanced efficiency and stability
Organic Electronics ( IF 2.7 ) Pub Date : 2018-09-25 , DOI: 10.1016/j.orgel.2018.09.027
Chao Ji , Chunjun Liang , Huimin Zhang , Mengjie Sun , Fulin Sun , Qi Song , Xuewen Zhang , Dan Li , Fangtian You , Zhiqun He

Perovskite solar cells (PSCs) are promising low-cost photovoltaic technologies with high solar-to-electric power conversion efficiency (PCE). Preparation of high-quality perovskite thin films is key to achieve high performance for PSCs. In this work, a small amount of fullerene (C60) is added to toluene in the antisolvent dripping process. The resulting C60-containing perovskite solar cells show better stability, PCE, and reproducibility than the device fabricated by using only toluene as an antisolvent. C60 adheres to the pinhole and grain boundaries of perovskite film, improves perovskite crystallinity, and enhances absorption without changing the thickness of the film. It also plays a passivation role on the surface of perovskite film and prevents the migration of I and Pb elements. The change of the morphology and the passivation of the interface increase the FF and JSC of C60-containing device. The best PCE of 19.8% is obtained. The PCE of encapsulated PSCs still maintains 70% of its initial value after 1000 h continuous full sun illumination.



中文翻译:

用于钙钛矿太阳能电池的C 60辅助晶体工程,具有更高的效率和稳定性

钙钛矿太阳能电池(PSC)是具有高太阳能到电功率转换效率(PCE)的有前途的低成本光伏技术。高质量钙钛矿薄膜的制备是实现PSC高性能的关键。在这项工作中,在反溶剂滴加过程中,将少量的富勒烯(C 60)添加到甲苯中。与仅使用甲苯作为抗溶剂制造的器件相比,所得的含C 60的钙钛矿太阳能电池表现出更好的稳定性,PCE和可重复性。C 60附着在钙钛矿薄膜的针孔和晶界上,改善了钙钛矿的结晶度,并在不改变薄膜厚度的情况下提高了吸收率。它还在钙钛矿薄膜表面上起钝化作用,并防止I和Pb元素迁移。形态的改变和界面的钝化增加了含C 60的器件的FF和J SC。获得了19.8%的最佳PCE。连续充满阳光照射1000小时后,封装的PSC的PCE仍保持其初始值的70%。

更新日期:2018-09-25
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