Oxidative cross-coupling reaction of catechols with active methylene compounds in an aqueous medium using an AlPO4-supported Ru catalyst†,Catalysis Science & Technology

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Oxidative cross-coupling reaction of catechols with active methylene compounds in an aqueous medium using an AlPO4-supported Ru catalyst†
Catalysis Science & Technology ( IF 5 ) Pub Date : 2018-09-25 00:00:00 , DOI: 10.1039/c8cy01425f
Zen Maeno _{1,

2,

3,

4} , Masanobu Yamamoto _{4,

5,

6,

7,

8} , Takato Mitsudome _{4,

5,

6,

7,

8} , Tomoo Mizugaki _{4,

5,

6,

7,

8} , Koichiro Jitsukawa _{4,

5,

6,

7,

8}

Affiliation

A green oxidative coupling reaction of catechols with active methylene compounds was achieved using an AlPO₄-supported Ru catalyst, where O₂ and H₂O were used as the ideal oxidant and solvent, respectively. The catalyst is easily separable, reusable and applicable for gram-scale syntheses.

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