The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy†,Chemical Communications

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The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-09-25 00:00:00 , DOI: 10.1039/c8cc05176c
Thomas Dumas _{1,

2,

3,

4,

5} , Dominique Guillaumont _{1,

2,

3,

4,

5} , Philippe Moisy _{1,

2,

3,

4,

5} , David K. Shuh _{6,

7,

8,

9} , Tolek Tyliszczak _{7,

8,

9,

10,

11} , Pier Lorenzo Solari _{5,

12,

13} , Christophe Den Auwer _{1,

2,

3,

4,

5}

Affiliation

In molecular solids derived from Prussian blue, intermetallic charge transfer is fostered through a cyano bridge two metal ions. In this study, isostructural trivalent lanthanide and tetravalent actinide Prussian blue analogs’ valence orbitals are probed by soft X-ray absorption measurements.

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