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Case Studies in Nanocluster Synthesis and Characterization: Challenges and Opportunities
Accounts of Chemical Research ( IF 16.4 ) Pub Date : 2018-09-21 00:00:00 , DOI: 10.1021/acs.accounts.8b00329 Andrew W. Cook 1 , Trevor W. Hayton 1
Accounts of Chemical Research ( IF 16.4 ) Pub Date : 2018-09-21 00:00:00 , DOI: 10.1021/acs.accounts.8b00329 Andrew W. Cook 1 , Trevor W. Hayton 1
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Atomically precise nanoclusters (APNCs) are an emerging area of nanoscience. Their monodispersity and well-defined arrangement of capping ligands facilitates the interrogation of their fundamental physical properties, allowing for the development of structure–function relationships, as well as their optimization for a variety of applications, including quantum computing, solid-state memory, catalysis, sensing, and imaging. However, APNCs present several unique synthetic and characterization challenges. For example, nanocluster syntheses are infamously low yielding and often generate complicated mixtures. This combination of factors makes nanocluster purification and characterization more difficult than that of typical inorganic or organometallic complexes. Yet, while this fact is undoubtedly true, the past lessons learned from the characterization of inorganic complexes are still useful today.
中文翻译：
纳米簇合成与表征的案例研究：挑战与机遇
原子精确的纳米簇（APNC）是纳米科学的新兴领域。它们的单分散性和明确定义的封端配体排列有助于对其基本物理性质的询问，从而促进结构-功能关系的发展，以及针对各种应用的优化，包括量子计算，固态记忆，催化，感应和成像。但是，APNC提出了一些独特的合成和表征挑战。例如，纳米团簇的合成臭名昭著的低产率并且经常产生复杂的混合物。这些因素的组合使得纳米簇的纯化和表征比典型的无机或有机金属配合物更难。然而，尽管这一事实无疑是对的，
更新日期：2018-09-21
中文翻译：
纳米簇合成与表征的案例研究：挑战与机遇
原子精确的纳米簇（APNC）是纳米科学的新兴领域。它们的单分散性和明确定义的封端配体排列有助于对其基本物理性质的询问，从而促进结构-功能关系的发展，以及针对各种应用的优化，包括量子计算，固态记忆，催化，感应和成像。但是，APNC提出了一些独特的合成和表征挑战。例如，纳米团簇的合成臭名昭著的低产率并且经常产生复杂的混合物。这些因素的组合使得纳米簇的纯化和表征比典型的无机或有机金属配合物更难。然而，尽管这一事实无疑是对的，
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