To improve the photocatalytic performance of Bi₂MoO₆, novel ternary heterojunctions of Pd/g-C₃N₄/Bi₂MoO₆ (Pd/CN/BMO) hollow microspheres were fabricated through g-C₃N₄ coupling via solvothermal precipitation-calcination and metallic Pd deposition by photoreduction method. The optimal ternary 2Pd/10CN/BMO photocatalyst exhibited the highest photocatalytic efficiency towards Rhodamine B (RhB) degradation with a degradation rate of 97% under 40 min visible light irradiation, 77%, 61% and 18% higher than that of the single BMO (20%), binary 2Pd/10CN (61%) and 10CN/BMO (79%), respectively. The enhanced photocatalytic performance was mainly ascribed to the synergetic effect of heterojunction structures between g-C₃N₄ and Bi₂MoO₆ and the surface plasmon resonance (SPR) effect of Pd doping, resulting in the better optical absorption ability and lower combination rate of photogenerated charge carriers. Additionally, the 2Pd/10CN/BMO composite presented excellent photo-stability in recycling experiments. The trapping experiments demonstrated that the O₂⁻, h⁺ and OH were separately the dominant, minor and the least important reactive species toward RhB degradation.

为了提高Bi ₂ MoO ₆的光催化性能，通过gC ₃ N ₄制备了新型的Pd / gC ₃ N ₄ / Bi ₂ MoO ₆（Pd / CN / BMO）中空微球三元异质结。溶剂热沉淀-煅烧和光还原法沉积金属Pd的偶合 最佳三元2Pd / 10CN / BMO光催化剂对罗丹明B（RhB）的降解表现出最高的光催化效率，在40分钟可见光照射下的降解率为97％，比单一BMO分别高77％，61％和18％。 （20％），二元2Pd / 10CN（61％）和10CN / BMO（79％）。增强的光催化性能主要归因于gC ₃ N ₄与Bi ₂ MoO ₆之间异质结结构的协同作用。Pd掺杂的表面等离振子共振（SPR）效应，导致更好的光吸收能力和较低的光生载流子结合率。此外，2Pd / 10CN / BMO复合材料在回收实验中表现出出色的光稳定性。陷印实验表明，ø ₂ ^-，H ⁺和OH产物中单独的主导，次要和朝向罗丹明B降解最不重要的反应性物种。