Cyclodextrin‐Based [3]Rotaxane‐Crosslinked Fluorescent Polymer: Synthesis and De‐Crosslinking Using Size Complementarity,Angewandte Chemie International Edition

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Cyclodextrin‐Based [3]Rotaxane‐Crosslinked Fluorescent Polymer: Synthesis and De‐Crosslinking Using Size Complementarity
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2018-10-15 , DOI: 10.1002/anie.201809171
Yosuke Akae ₁ , Hiromitsu Sogawa ₁ , Toshikazu Takata ₁

Affiliation

Vinyl‐group‐substituted, α‐cyclodextrin‐based, size‐complementary [3]rotaxanes were synthesized as crosslinkers for rotaxane‐crosslinked poly(methyl methacrylate) (RCP) by radical polymerization. The size complementarity of the crosslinkers made it possible to de‐crosslink the RCP by heating, and the degree of decoupling was monitored by fluorescence intensity, depending on the state of the axle component of the rotaxane crosslink moiety.

中文翻译：

基于环糊精的[3]轮烷交联的荧光聚合物：使用尺寸互补性的合成和去交联

通过自由基聚合合成了乙烯基取代的，基于α-环糊精的，尺寸互补的[3]轮烷，作为轮烷交联的聚甲基丙烯酸甲酯（RCP）的交联剂。交联剂的大小互补性使通过加热使RCP交联成为可能，并且根据轮烷交联部分的轴成分的状态，通过荧光强度监测去偶联的程度。

更新日期：2018-10-15

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