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A new porous structure with dispersed nano-TiO2 in a three-dimensional carbon skeleton for achieving high photocatalytic activity
Microporous and Mesoporous Materials ( IF 4.8 ) Pub Date : 2018-09-20 , DOI: 10.1016/j.micromeso.2018.09.021
Jia-Hao Jhang , Shinn-Jen Chang , Sireesha Pedaballi , Chia-Chen Li

A new photocatalyst is proposed that incorporates TiO2 nanopowder into a three-dimensional carbon skeleton to create a TiO2/C porous microsphere with adjustable pore size, and its photocatalytic activity is investigated and compared to that of a commercially available photocatalytic powder (P25). The photocatalytic efficiency of the proposed TiO2/C porous microsphere achieves a considerable improvement of more than 2–3 times that of P25 when irradiated by UV and visible lights. With the further incorporation of Fe, the TiO2/C/Fe porous microsphere exhibits maximum photodegradation efficiencies of 97% and 45% when low-power UV and visible lights are the energy sources, respectively; these are significantly higher than the 40% and 10% measured for P25. In addition, the major mechanism for this improvement in photocatalytic activity by the porous microsphere is identified by calculating band gap energies based on a modified Kubelka-Munk function.



中文翻译:

一种新型的多孔结构,其在三维碳骨架中分散有纳米TiO 2,可实现高光催化活性

提出了一种新的光催化剂,该方法将TiO 2纳米粉体整合到三维碳骨架中,以创建孔径可调的TiO 2 / C多孔微球,并对其光催化活性进行了研究,并与市售的光催化粉末(P25)进行了比较。 。所提议的TiO 2 / C多孔微球的光催化效率,在受到紫外线和可见光照射时,可达到P25的2-3倍以上的显着提高。随着铁的进一步掺入,TiO 2当低功率紫外线和可见光为能源时,/ C / Fe多孔微球的最大光降解效率分别为97%和45%。这些显着高于P25测得的40%和10%。此外,通过基于改进的Kubelka-Munk函数计算带隙能,可以确定多孔微球改善光催化活性的主要机理。

更新日期:2018-09-20
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