Cyanomethyl anion transfer reagents for diastereoselective Corey–Chaykovsky cyclopropanation reactions†,Chemical Communications

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Cyanomethyl anion transfer reagents for diastereoselective Corey–Chaykovsky cyclopropanation reactions†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-09-20 00:00:00 , DOI: 10.1039/c8cc05602a
Renè Hommelsheim _{1,

2,

3,

4} , Katharina J. Hock _{1,

2,

3,

4} , Christian Schumacher _{1,

2,

3,

4} , Mohanad A. Hussein _{5,

6,

7} , Thanh V. Nguyen _{5,

6,

7} , Rene M. Koenigs _{1,

2,

3,

4}

Affiliation

A readily available and bench-stable cyanomethyl sulfonium salt was used in highly diastereoselective Corey–Chaykovsky cyclopropanation reactions of electron-poor olefins. This efficient method provides a rapid route to access densely functionalized cyclopropyl nitriles.

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