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Novel high-gluten flour physically cross-linked graphene oxide composites: Hydrothermal fabrication and adsorption properties for rare earth ions
Ecotoxicology and Environmental Safety ( IF 6.8 ) Pub Date : 2018-09-18 , DOI: 10.1016/j.ecoenv.2018.09.062
Xia Xu , Jiao Zou , Jie Teng , Qi Liu , Xin-Yu Jiang , Fei-Peng Jiao , Jin-Gang Yu , Xiao-Qing Chen

Graphene oxide (GO) nanosheets were immobilized and cross-linked by high-gluten flour (HGF), and a series of biomass-GO composites with various HGF-to-GO mass ratios were fabricated through a one-step hydrothermal method. The HGF-GO composites were used as novel adsorbents to adsorb rare earth ions (REE3+: La3+, Yb3+, Y3+, Er3+ and Nd3+) from aqueous solutions, and their adsorption properties were also investigated detailly. To evaluate the physicochemical properties of HGF-GO composites and further understand the mechanisms of adsorption of REE3+ onto HGF-GO composites, the HGF-GO composites were characterized by scanning electron microscopy (SEM), thermal gravimetric analyzer (TGA), Raman spectroscopy and Fourier transform infrared (FT-IR) spectroscopy. Several important condition parameters including contact time, initial REE3+concentrations, solution pH values and temperature that might affect the adsorption process were studied in detail. The maximum adsorption capacities of HGF-GO1:1 composite toward La3+, Yb3+, Y3+, Er3+ and Nd3+ were 30.32, 36.64, 32.84, 42.36 and 48.68 mg g−1, respectively. The experimental data indicated that the adsorption of REE3+ onto HGF-GO1:1 was well fitted by the pseudo-second order kinetic model and the Langmuir isotherm model, and the adsorption process was a spontaneous and endothermic reaction. The HGF-GO1:1 composite could be well regenerated and reused after five adsorption-desorption cycles, and its removal efficiency for Yb3+ remained as a constant of 100%.



中文翻译:

新型高筋面粉物理交联氧化石墨烯复合材料:稀土离子的水热制备和吸附性能

通过高筋面粉(HGF)固定并交联氧化石墨烯(GO)纳米片,并通过一步水热法制备了具有不同HGF / GO质量比的一系列生物质-GO复合材料。将HGF-GO复合材料作为新型吸附剂从水溶液中吸附稀土离子(REE 3+:La 3+,Yb 3+,Y 3+,Er 3+和Nd 3+),并且它们的吸附性能也很强。详细调查。评估HGF-GO复合材料的理化性质,并进一步了解REE 3+的吸附机理在HGF-GO复合材料上,通过扫描电子显微镜(SEM),热重分析仪(TGA),拉曼光谱和傅里叶变换红外(FT-IR)光谱对HGF-GO复合材料进行了表征。详细研究了可能影响吸附过程的几个重要条件参数,包括接触时间,初始REE 3+浓度,溶液pH值和温度。HGF-GO 1:1复合材料对La 3+,Yb 3+,Y 3+,Er 3+和Nd 3+的最大吸附容量分别为30.32、36.64、32.84、42.36和48.68 mg g -1。实验数据表明REE 3+的吸附拟二阶动力学模型和Langmuir等温模型很好地拟合了HGF-GO 1:1上的吸附,吸附过程为自发吸热反应。在五个吸附-解吸循环后,HGF-GO 1:1复合材料可以很好地再生和再利用,其对Yb 3+的去除效率保持恒定为100%。

更新日期:2018-09-18
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