Recent progress in macrocyclic amphiphiles and macrocyclic host-based supra-amphiphiles,Materials Chemistry Frontiers

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Recent progress in macrocyclic amphiphiles and macrocyclic host-based supra-amphiphiles
Materials Chemistry Frontiers ( IF 6.0 ) Pub Date : 2018-09-19 00:00:00 , DOI: 10.1039/c8qm00314a
Huangtianzhi Zhu _{1,

2,

3,

4,

5} , Liqing Shangguan _{1,

2,

3,

4,

5} , Bingbing Shi _{1,

2,

3,

4,

5} , Guocan Yu _{6,

7,

8,

9,

10} , Feihe Huang _{1,

2,

3,

4,

5}

Affiliation

Macrocycle-based amphiphiles, including macrocyclic amphiphiles and macrocyclic host-based supra-amphiphiles, are a class of amphiphiles which are capable of self-assembling into multidimensional assemblies with defined nanostructures. By involving host–guest recognition, these amphiphiles can be tailored to fabricate new topological structures and fulfill multiple applications. Compared with covalent-bonded traditional amphiphiles and polymeric amphiphiles, the introduction of host–guest interactions facilitates the design, synthesis and controllability of these amphiphilic systems. Moreover, host–guest interactions usually possess stimuli-responsive properties, which further endow self-assemblies of macrocycle-based amphiphiles with fantastic functions. In this review, we summarize recent progress in macrocyclic amphiphiles and macrocyclic host-based supra-amphiphiles, with a focus on novel functions and applications of self-assemblies of these amphiphiles.

中文翻译：

大环两亲物和基于大环宿主的超两亲物的最新进展

基于大环的两亲物，包括大环的两亲物和基于大环的宿主的超两亲物，是一类能够自组装成具有定义的纳米结构的多维组装体的两亲物。通过涉及主客体识别，可以对这些两亲物进行定制以制造新的拓扑结构并满足多种应用。与共价键结合的传统两亲物和聚合物两亲物相比，宿主-客体相互作用的引入促进了这些两亲物系统的设计，合成和可控性。而且，宿主与客体之间的相互作用通常具有刺激响应特性，这进一步使基于大环的两亲物的自组装具有出色的功能。在这篇评论中，

更新日期：2018-09-19

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