Unveiling the role of choline chloride in furfural synthesis from highly concentrated feeds of xylose,Green Chemistry

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Unveiling the role of choline chloride in furfural synthesis from highly concentrated feeds of xylose
Green Chemistry ( IF 9.3 ) Pub Date : 2018-09-19 , DOI: 10.1039/c8gc02260g
S. Jiang _{1,

2,

3} , C. Verrier _{4,

5,

6,

7,

8} , M. Ahmar _{4,

5,

6,

7,

8} , J. Lai _{9,

10,

11,

12} , C. Ma _{9,

10,

11,

12} , E. Muller _{3,

13,

14,

15} , Y. Queneau _{4,

5,

6,

7,

8} , M. Pera-Titus _{9,

10,

11,

12} , F. Jérôme _{1,

2,

3} , K. De Oliveira Vigier _{1,

2,

3}

Affiliation

Furfural is a biomass derived compound used for the synthesis of fuels and chemicals. Herein we show that choline chloride allows the conversion of highly concentrated feeds of xylose (up to 50 wt%) to furfural (up to 75%) and that it can be recycled. Such a beneficial effect was observed from the formation of a choline xyloside intermediate exhibiting higher reactivity than xylose.

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