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MOF based on a longer linear ligand: electrochemical performance, reaction kinetics, and use as a novel anode material for sodium-ion batteries†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-09-18 00:00:00 , DOI: 10.1039/c8cc06248j
Yan Zhang 1, 2, 3, 4, 5 , Shihui Yang 5, 6, 7, 8 , Xiaoya Chang 1, 2, 3, 4, 5 , Huinan Guo 1, 2, 3, 4, 5 , Yunwei Li 1, 2, 3, 4, 5 , Mengying Wang 1, 2, 3, 4, 5 , Weinqin Li 1, 2, 3, 4, 5 , Lifang Jiao 1, 2, 3, 4, 5 , Yijing Wang 1, 2, 3, 4, 5
Affiliation  

A metal–organic framework based on a longer linear ligand was rationally designed and evaluated as a novel anode material for sodium-ion batteries. It delivered a high specific capacity of 269 mA h g−1 with a desired voltage plateau and demonstrated excellent capacity retention (79.0% after 1000 cycles). In addition, its reaction kinetics was also investigated in detail by performing cyclic voltammetry and a predominantly diffusion-controlled process was clearly revealed.

中文翻译:

基于更长的线性配体的MOF:电化学性能,反应动力学,并用作钠离子电池的新型负极材料

基于更长的线性配体的金属-有机骨架被合理地设计和评价为钠的新颖的阳极材料-离子电池。它提供了269 mA hg -1的高比容量,并具有所需的电压平稳范围,并显示出出色的容量保持率(1000次循环后为79.0%)。此外,还通过循环伏安法详细研究了其反应动力学,并清楚地揭示了主要的扩散控制过程。
更新日期:2018-09-18
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