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Multimetallic Lanthanide Complexes: Using Kinetic Control To Define Complex Multimetallic Arrays
Accounts of Chemical Research ( IF 16.4 ) Pub Date : 2018-09-17 00:00:00 , DOI: 10.1021/acs.accounts.8b00205
Thomas Just Sørensen 1 , Stephen Faulkner 2
Affiliation  

Kinetically inert lanthanide complexes are proving to be highly effective building blocks for the preparation of complex heterometallic architectures, allowing complete control of metal ion domains, which cannot be achieved under thermodynamic control. Kinetic stability may render perceivable labile coordination bonds more durable than several types of covalent interactions. For complexes in clinical use, the significance of kinetic stability cannot be overstated, and this Account treats the topic accordingly.

中文翻译:

多金属镧系元素络合物:使用动力学控制定义复杂的多金属阵列

动力学惰性的镧系元素络合物被证明是制备复杂的异金属结构的高效构件,可以完全控制金属离子域,这在热力学控制下是无法实现的。动力学稳定性可使可感知的不稳定配位键比几种类型的共价相互作用更持久。对于临床使用的复合物,动力学稳定性的重要性不可低估,因此本帐户将相应地处理该主题。
更新日期:2018-09-17
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