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High thermal stability of electric field-induced strain in (1−x)(Bi0.5Na0.5)TiO3-xBa0.85Ca0.15Ti0.9Zr0.1O3 lead-free ferroelectrics
Journal of the European Ceramic Society ( IF 5.8 ) Pub Date : 2018-09-17 , DOI: 10.1016/j.jeurceramsoc.2018.09.019
Li Jin , Wenting Luo , Liang Wang , Ye Tian , Qingyuan Hu , Lei Hou , Lin Zhang , Xu Lu , Hongliang Du , Xiaoyong Wei , Gang Liu , Yan Yan

In ferroelectric materials high electric field-induced strain (EFIS) with good thermal stability is of much interest from both fundamental research and potential applications. Here we propose a strategy to achieve high thermally stable EFIS based on electrostrictive effect and thermal stability of polarization. According to this strategy, we synthesized (1−x)(Bi0.5Na0.5)TiO3-xBa0.85Ca0.15Ti0.9Zr0.1O3 (BNT-xBCZT) ferroelectric ceramics in order to tailor the thermal stability of dielectric permittivity, polarization and EFIS. A dielectric platform with a wide temperature region is induced by increasing x from 0.24 to 0.36 gradually. From 30 °C to 150 °C, a variation of 20% polarization results in a change of 36% EFIS, suggesting a good thermal stability as expect. Temperature-insensitive electrostrictive coefficient Q33 ranges from 0.0264 m4/C2 to 0.0314 m4/C2. These results not only prove the effectiveness of this strategy, but also suggest that this strategy can be applied to other ferroelectric materials to improve the thermal stability.



中文翻译:

(1- x)(Bi 0.5 Na 0.5)TiO 3 - x Ba 0.85 Ca 0.15 Ti 0.9 Zr 0.1 O 3无铅铁电材料中电场引起的应变的高热稳定性

在铁电材料中,基础研究和潜在应用都对具有良好热稳定性的高电场感应应变(EFIS)感兴趣。在这里,我们提出一种基于电致伸缩效应和极化热稳定性来实现高热稳定性EFIS的策略。根据该策略,我们合成了(1- x)(Bi 0.5 Na 0.5)TiO 3 - x Ba 0.85 Ca 0.15 Ti 0.9 Zr 0.1 O 3(BNT- xBCZT)铁电陶瓷,以调整介电常数,极化和EFIS的热稳定性。通过将x从0.24逐渐增加到0.36,可以感应出具有宽温度范围的介电平台。从30°C到150°C,极化变化20%导致EFIS发生36%的变化,这表明了良好的热稳定性。对温度不敏感的电致伸缩系数Q 33为0.0264m 4 / C 2至0.0314m 4 / C 2。这些结果不仅证明了该策略的有效性,而且表明该策略可以应用于其他铁电材料以提高热稳定性。

更新日期:2018-09-17
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