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A G4·K+ hydrogel made from 5′-hydrazinoguanosine for remediation of α,β-unsaturated carbonyls†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-09-17 00:00:00 , DOI: 10.1039/c8cc07228k
Songjun Xiao 1, 2, 3 , Jeffery T. Davis 1, 2, 3
Affiliation  

A G4·K+ hydrogel made from 5′-hydrazinoguanosine and KCl reacts with α,β-unsaturated carbonyls of different electrophilicities (acrolein, methyl vinyl ketone and methyl acrylate) in water and the gas phase to form cyclic adducts. This aza-Michael addition/cyclization domino reaction by the 5′-hydrazino G4·K+ hydrogel has promise for environmental remediation of toxic α,β-unsaturated carbonyls from water and the atmosphere.

中文翻译:

由5'-肼基苷制成的 AG 4 ·K +水凝胶,可修复α,β-不饱和羰基

由5'-肼基鸟苷和KCl制成的AG 4 ·K +水凝胶在水中和气相中与具有不同亲电性的α,β-不饱和羰基(丙烯醛,甲基乙烯基酮和丙烯酸甲酯)反应,形成环状加合物。5'-肼基G 4 ·K +水凝胶的氮杂-迈克尔加成/环化多米诺反应有望从环境中修复水和大气中有毒的α,β-不饱和羰基。
更新日期:2018-09-17
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