Four coordination polymers, [CuCl(cptpy)∙2H₂O]_n(1), [Mn₂Cl₂(cptpy)₂(phdat)H₂O]_n(2) and [Ln(cptpy)₃]_n (Ln = La (3), Pr (4)) (Hcptpy = 4'-(4-carboxyphenyl)−2,2':6',2''-terpyridine, phdat = 2,4-diamino-6-phenyl-triazine) have been hydrothermally synthesized and characterized by IR spectra, X-ray single-crystal diffraction, powder X-ray diffraction (PXRD), elemental analyses and thermogravimetric analyses (TGA). Compounds 1, 3 and 4 exhibit 2D or 3D structures comprising 1D linear chain connected by π…π stacking interactions. While, compound 2 contains two kinds of 1D chains, of which one is a linear chain and the other is a ladder chain, and further extends to 3D structure by π…π stacking and hydrogen bonding interactions. The electrochemical analysis shows that compound 1 has good catalytic activities for the reductions of both NaNO₂ and H₂O₂, and is a potential catalytic material. Magnetic analysis indicates that compound 2 exhibits antiferromagnetic behavior.

四种配位聚合物[CuCl（cptpy）∙2H ₂ O] _n （1），[Mn ₂ Cl ₂（cptpy）₂（phdat）H ₂ O] _n （2）和[Ln（cptpy）₃ ] _n（Ln = La（3），Pr（4））（Hcptpy = 4'-（4-羧苯基）-2,2'：6'，2''-吡啶，phdat = 2,4-二氨基-6-苯基-三嗪已通过水热合成并通过红外光谱，X射线单晶衍射，粉末X射线衍射（PXRD），元素分析和热重分析（TGA）进行了表征。化合物1，3和4展示2D或3D结构，其中包含通过π…π堆积相互作用连接的1D线性链。同时，化合物2包含两种一维链，其中一种是直链，另一种是梯链，并通过π…π堆积和氢键相互作用进一步延伸到3D结构。电化学分析表明，化合物1具有用于还原NaNO ₂和H ₂ O _2的良好催化活性，并且是潜在的催化材料。磁分析表明化合物2表现出反铁磁行为。