Highly efficient and selective visible-light driven CO2-to-CO conversion by a Co-based cryptate in H2O/CH3CN solution†,Chemical Communications

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Highly efficient and selective visible-light driven CO2-to-CO conversion by a Co-based cryptate in H2O/CH3CN solution†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-09-14 00:00:00 , DOI: 10.1039/c8cc04892d
Dong-Cheng Liu _{1,

2,

3} , Hong-Juan Wang _{3,

4,

5,

6,

7} , Jia-Wei Wang _{1,

2,

3} , Di-Chang Zhong _{3,

4,

5,

6,

7} , Long Jiang _{1,

2,

3} , Tong-Bu Lu _{1,

2,

3,

4,

5}

Affiliation

Herein, we report a mononuclear Co(II) cryptate which exhibits highly efficient and selective photocatalytic CO₂-to-CO conversion in H₂O/CH₃CN solution. The TON and selectivity reach as high as 51 392 and 98%, respectively.

中文翻译：

在H ₂ O / CH ₃ CN解决方案中通过基于Co的加密物高效高效地进行选择性可见光驱动的CO ₂到CO转换†

在本文中，我们报告了单核Co（II）加密物，它在H ₂ O / CH ₃ CN溶液中表现出高效和选择性的光催化CO ₂到CO转化。TON和选择性分别高达51 392和98％。

更新日期：2018-09-14

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