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Dry particle coating preparation of highly conductive LaMnO3@C composite for the oxygen reduction reaction and hydrogen peroxide sensing
Journal of the Taiwan Institute of Chemical Engineers ( IF 5.7 ) Pub Date : 2018-09-13 , DOI: 10.1016/j.jtice.2018.08.032
Chelladurai Karuppiah , Karuppasamy Kohila rani , Sea-Fue Wang , Rajkumar Devasenathipathy , Chun-Chen Yang

Hydrogen peroxide (H2O2) sensing and oxygen reduction reaction (ORR) has considered to be a highly desirable in the areas of sensing and energy production. In recent years, researchers focus on the replacement of noble metal-based electrocatalyst used for the ORR and H2O2 sensing by low-cost materials. In this current work, we have synthesized carbon black supported LaMnO3 ([email protected]) via dry particle coating method and studied its electrocatalytic activity towards ORR and H2O2 sensing. The characterization of synthesized [email protected] was performed by using field emission scanning electron microscopy (FESEM), energy dispersive X-ray (EDX) spectroscopy, transmission electron microscopy (TEM), X-ray diffraction (XRD) spectroscopy, X-ray photoelectron spectroscopy (XPS), and Raman spectroscopy techniques. Furthermore, the synergistic effect between LMO and carbon was established through electrochemical measurements. In case of ORR, our prepared [email protected] composite possess longer life-time (89.8%) than 20 wt% Pt/C (77.6%). In another case, this electrocatalyst ([email protected]) owns wide working range, low limits of detection and high sensitivity for the determination of H2O2. The experimental data of [email protected] towards the electrochemical sensing of H2O2 and ORR demonstrates its potential applications in the construction of sensors and energy generation devices.



中文翻译:

用于氧还原反应和过氧化氢传感的高导电LaMnO 3 @C复合材料的干粉涂层制备

在感测和能量产生领域中,过氧化氢(H 2 O 2)感测和氧还原反应(ORR)被认为是高度期望的。近年来,研究人员致力于用低成本材料替代用于ORR和H 2 O 2感测的贵金属基电催化剂。在当前的工作中,我们通过干法颗粒涂覆法合成了炭黑负载的LaMnO 3([受电子邮件保护]),并研究了其对ORR和H 2 O 2的电催化活性。感应。通过使用场发射扫描电子显微镜(FESEM),能量色散X射线(EDX)光谱,透射电子显微镜(TEM),X射线衍射(XRD)光谱,X射线对合成的[受电子邮件保护的]进行表征光电子能谱(XPS)和拉曼光谱技术。此外,通过电化学测量确定了改性活生物体与碳之间的协同作用。对于ORR,我们制备的[受电子邮件保护的]复合材料的使用寿命(89.8%)比20 wt%的Pt / C(77.6%)长。在另一种情况下,这种电催化剂([受电子邮件保护])具有较宽的工作范围,较低的检测限和对H 2 O 2测定的高灵敏度。对H 2 O 2和ORR进行电化学检测的[受电子邮件保护]的实验数据证明了其在传感器和能量产生装置的构造中的潜在应用。

更新日期:2018-09-13
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