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Combining Oxoammonium Cation Mediated Oxidation and Photoredox Catalysis for the Conversion of Aldehydes into Nitriles
Synlett ( IF 1.7 ) Pub Date : 2018-09-12 , DOI: 10.1055/s-0037-1610272
Nicholas Leadbeater 1 , Jyoti Nandi , Mason Witko
Affiliation  

A method to oxidize aromatic aldehydes to nitriles has been developed. It involves a dual catalytic system of 4-acetamido-TEMPO and visible-light photoredox catalysis. The reaction is performed using ammonium persulfate as both the terminal oxidant and nitrogen source.

中文翻译:

结合氧铵阳离子介导的氧化和光氧化还原催化将醛转化为腈

已开发出一种将芳香醛氧化成腈的方法。它涉及 4-乙酰氨基-TEMPO 和可见光光氧化还原催化的双重催化系统。该反应使用过硫酸铵作为末端氧化剂和氮源进行。
更新日期:2018-09-12
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