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Long-Chain Hyperbranched Polymers: Synthesis, Properties, and Applications.
Macromolecular Rapid Communications ( IF 4.2 ) Pub Date : 2018-09-12 , DOI: 10.1002/marc.201800471 Bin Mu 1 , Tingting Liu 1 , Wei Tian 1
Macromolecular Rapid Communications ( IF 4.2 ) Pub Date : 2018-09-12 , DOI: 10.1002/marc.201800471 Bin Mu 1 , Tingting Liu 1 , Wei Tian 1
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By combining the virtues of conventional linear and hyperbranched polymers, long-chain hyperbranched polymers (LCHBPs) have attracted great attention. Therefore, a comprehensive summary of the research progress of LCHBPs is presented, with a particular focus on their synthetic strategies, unique properties, and potential applications. The synthetic methodologies are rationalized into four main classes according to their construction process or mechanism, namely ABx (x ≥ 2), A2 + Bx (x ≥ 3), AB + ABx (x ≥ 2), and self-condensing vinyl polymerization. Some of their rheological properties, self-assembly behavior, and stimuli-response features are then discussed. Finally, the emergent applications including biomedicine, electrical conductivity, chemical sensing, and catalyst carrier, are outlined. It is anticipated that this review will stimulate more inspiration for advancing the development of this novel kind of LCHBP.
中文翻译：
长链超支化聚合物：合成，性质和应用。
通过结合常规线性和超支化聚合物的优点，长链超支化聚合物（LCHBPs）引起了极大的关注。因此，本文对LCHBPs的研究进展进行了全面的总结，特别关注LCHBPs的合成策略，独特性能和潜在应用。合成方法根据其构建过程或机理分为四个主要类别，即ABx（x≥2），A2 + Bx（x≥3），AB + ABx（x≥2）和自缩合乙烯基聚合。然后讨论了它们的一些流变特性，自组装行为和刺激响应特征。最后，概述了新兴应用，包括生物医学，电导率，化学传感和催化剂载体。
更新日期：2018-09-12
中文翻译：
长链超支化聚合物：合成，性质和应用。
通过结合常规线性和超支化聚合物的优点，长链超支化聚合物（LCHBPs）引起了极大的关注。因此，本文对LCHBPs的研究进展进行了全面的总结，特别关注LCHBPs的合成策略，独特性能和潜在应用。合成方法根据其构建过程或机理分为四个主要类别，即ABx（x≥2），A2 + Bx（x≥3），AB + ABx（x≥2）和自缩合乙烯基聚合。然后讨论了它们的一些流变特性，自组装行为和刺激响应特征。最后，概述了新兴应用，包括生物医学，电导率，化学传感和催化剂载体。
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