Ultrasound-induced gelation of a giant macrocycle†,Chemical Communications

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Ultrasound-induced gelation of a giant macrocycle†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-09-11 00:00:00 , DOI: 10.1039/c8cc04742a
Diego Núñez-Villanueva _{1,

2,

3,

4,

5} , Michael A. Jinks _{1,

2,

3,

4,

5} , Jorge Gómez Magenti _{1,

2,

3,

4,

5} , Christopher A. Hunter _{1,

2,

3,

4,

5}

Affiliation

A 68-membered macrocycle undergoes ultrasound-induced supramolecular gelation in acetonitrile. The sonogel shows a remarkable thermostability, indicating that self-assembly is mediated by exceptionally robust non-covalent interactions. Model compounds indicate that the macrocyclic topology is essential for gelation to occur.

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