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Porous Shape-Persistent Organic Cage Compounds of Different Size, Geometry, and Function
Accounts of Chemical Research ( IF 16.4 ) Pub Date : 2018-09-11 00:00:00 , DOI: 10.1021/acs.accounts.8b00298 Michael Mastalerz 1
Accounts of Chemical Research ( IF 16.4 ) Pub Date : 2018-09-11 00:00:00 , DOI: 10.1021/acs.accounts.8b00298 Michael Mastalerz 1
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The interest in shape-persistent organic cages is nearly as old as the interest in supramolecular chemistry. In the beginning, organic cages have often been synthesized in a stepwise manner, which is not only laborious but very often also accompanied by low overall yields. In 1988, MacDowell published the one pot high-yielding synthesis of [2 + 3] imine cages based on TREN and aromatic dialdehydes, exploiting the reversible condensation of amines and aldehydes to imines, which was later used by others to make even larger cages on the basis of resorcinarenes.
中文翻译：
尺寸，几何形状和功能不同的多孔形状持久性有机笼化合物
对形状持久性有机笼子的兴趣几乎与对超分子化学的兴趣一样古老。最初，有机网箱通常是分步合成的，这不仅费力，而且总收率也很低。1988年，麦克道尔（MacDowell）发表了基于TREN和芳族二醛的[2 + 3]亚胺笼的一锅高产合成方法，该方法利用胺和醛的可逆缩合成亚胺，后来被其他人用来在间苯二酚的基础。
更新日期：2018-09-11
中文翻译：
尺寸，几何形状和功能不同的多孔形状持久性有机笼化合物
对形状持久性有机笼子的兴趣几乎与对超分子化学的兴趣一样古老。最初，有机网箱通常是分步合成的，这不仅费力，而且总收率也很低。1988年，麦克道尔（MacDowell）发表了基于TREN和芳族二醛的[2 + 3]亚胺笼的一锅高产合成方法，该方法利用胺和醛的可逆缩合成亚胺，后来被其他人用来在间苯二酚的基础。
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